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Batman investigates Scarecrow's presence, and searches for him in a rooftop safehouse, but instead finds and saves Poison Ivy, who was being held captive by Scarecrow's henchmen.
In a makeshift Batcave in Gotham's Clock Tower, Barbara Gordon is collecting information on Scarecrow's new toxin, and traces its production to Ace Chemicals.
Batman is also exposed to the toxin, which triggers a powerful hallucinogenic response.
He receives a message from Scarecrow revealing that Barbara is in the same safehouse where Ivy was held, but before Batman can save her, Barbara is doused with fear toxin and shoots herself in the head.
However, Batman refuses to be apprehended until Scarecrow has been stopped, and locks Robin in a holding cell.
Batman tracks the Arkham Knight to an underground tunnel network, but does not find him.On Halloween night, Scarecrow unleashes his newest strain of Fear Gas in a diner, and threatens to release it throughout Gotham.Six million civilians are evacuated, but the city's criminals and supervillains stay behind, leaving Commissioner James Gordon and the Gotham City Police Department outnumbered.As they confront Scarecrow, Barbara is revealed to still be alive, and her suicide was a fear toxin-induced hallucination.Having made a deal with Scarecrow for his daughter's life, Gordon shoots Batman in the chest, who falls from the roof.