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The Malleus Maleficarum (Hammer of Witches) is a manual written for witch hunters in the 15th century.
It is one of the most famously misogynistic works in European history; the book is a treatise on how women, due to their inferior and carnal natures, are far more susceptible to the Devil's wiles than are men.
There are also people who are self-taught -- no deals or mentors, just a book of spells.
It is notable that hunters like Sam, Dean and Bobby Singer often use spells and rituals, but would not consider themselves witches.
The Grand Coven ruled and controlled the affairs of witches and guarded the lore.
However, the Grand Coven and the witch community is now greatly weakened, after any years of attacks and witch hunts coupled with an organised effort by the Men of Letters to plunder them or their spell books and records, which they hid in various spell-guarded bunkers around the world.
Eventually Tammi is killed by Dean with Ruby's knife.
While the book was very popular, it wasn't necessarily the most influential witch-hunting text, other witch hunters seemed to consider it went a bit too far in its condemnation of women as a group, which limited its usefulness.
Two very old witches - Don Harding and Tracy Davis - begin sacrificing people in order to raise the demon Samhain from Hell.
It is revealed that most witches perform their magic through either chanting or placing a hex bag in the general area where their target is at the time of the spell.
Witches also use a magical tome known as a Book of Shadows or a grimoire.